GLOBAL WARMING AND CONSTRUCTION ASPECTS

Authors

  • Ghada Bassioni Ain Shams University (EG)

DOI:

https://doi.org/10.17770/etr2009vol2.1013

Keywords:

Green construction – Limestone – CO2 emission

Abstract

The manufacture of cements with several main constituents is of particular importance with regard to reducing climatically relevant CO2 emissions in the cement industry. This ecological aspect is not the only argument in favor of Portland composite cements. They are also viable alternatives to Portland cement from the technical point of view. Substitution of ordinary Portland cement (CEM I) by Portland composite cements (CEM II) and (CEM III), which clearly possess different chemical and mineralogical compositions, results in changes of their reaction behavior with additives like superplasticizers. A common admixture to CEM I in that sense is limestone (industrial CaCO3). Its interaction with polycarboxylates is ignored and its inertness is taken for granted. This study provides a systematic approach in order to better understand the interaction of these polymeric superplasticizers with CaCO3 by adsorption and zeta potential measurements. The results give some fundamental understanding in how far the cement industry can reduce the production of cement clinker by replacing it with limestone as admixture and consequently the CO2-emission is reduced, which is of high political and environmental interest.

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References

Guidance document for EPER implementation. European Commission Directorate - General for Environment, 2000.

Environmental Data of the Cement Industry. Verein Deutscher Zementwerke, e.V., Düsselorf, 2006.

Bundesverband der Deutschen Zementindustrie, e.V., Berlin, 2007.

Gabrovšek R., Vuk T., Kaučič V. Evaluation of the hydration of portland cement containing various carbonates by means of thermal analysis. Acta Chim Slov 2006. 53:159-65.

Plank J., Stephan D., Hirsch Ch. Construction Chemistry: Chemical Engineering Processes and Products. Wiley-VCH, Weinheim, 2004. p. 1-167.

Prince W., Edwards-Lajnef M., Aïtcin P.C. Interaction between ettringite and a polynaphthalene sulfonate superplasticizer in a cementitious paste. Cem Conc Res 2002. 32:79-85.

Sakai E., Nozaki T., Atarashi D., Daimon M. Interaction between superplasticizers and ecocement. CANMET International Conference on Superplasticizers and other Chemical Admixtures in Concrete, 2006. p. 227-37.

Backfolk K., Lagerge S., Rosenholm J.B., Eklund D. Aspects on the Interaction between Sodium Carboxymethylcellulose and Calcium Carbonate and the Relationship to Specific Site Adsorption. J Colloid Interface Sci, 2002. 248:5-12.

Abraham T. Effects of divalent salt on adsorption kinetics of a hydrophobically modified polyelectrolyte at the neutral surface-aqueous solution interface. Polymer, 2002. 43:849-55.

Plank J., Bassioni G. Adsorption of carboxylate anions on a CaCO3 surface. Z Naturfor B, 2007. 62b:1277-84.

Plank J., Bassioni G., Dai Z., Keller H., Sachsenhauser B., Zouaoui N. News about the interactions of cement and superplasticizers. ibausil Tagungsband, 2006. 16:579-98.

ASTM Annual Book of Standards, Vol. 04.01 Cement; Lime; Gypsum, American Society for Testing and Materials, West Conshohocken, PA, 2004.

Hawkins P., Tennis P., Detwiler R. The use of limestone in Portland cement: A state-of-the-art review. EB227, Portland Cement Association, Skokie, IL; 2003. p. 44.

Bonavetti V., Donza H., Menendez G., Cabrera O., Irassar E.F. Limestone filler cement in low w/c concrete: a rational use of energy. Cem Concr Res, 2003. 33:865-71.

Bentz D.P., Conway J.T. Computer modeling of the replacement of "coarse" cement particles by inert fillers in low w/c ratio concretes. Hydration and strength. Cem Concr Res. 2001. 31(3):503-6.

Bentz D.P. Replacement of "coarse" cement particles by inert fillers in low w/c ratio concretes. Cem Concr Res 2005. 35(1):185-8.

Bentz D.P. Modeling the influence of limestone filler on cement hydration using CEMHYD3D. J Cem Concr Comp, 2006. 28(2):124-9.

Gutteridge W.A., Dalziel J.A. Filler cement: The effect of the secondary component on the hydration of portland cement: Part I; A fine non-hydraulic filler. Cem Concr Res, 1990. 20:778-82.

Beedle S.S., Groves G.W., Rodger S.A. The effect of fine pozzolanic and other particles on the hydration of tricalcium silicate (C3S). Adv Cem Res, 1989. 2(5):3-8.

Moosberg-Bustnes H., Lotta L., Forssberg E. Fine particulate metallurgical by-products' influence on cement hydration and strength development: An initial study. Scan J Metal, 2004. 33:15-21.

Plank J., Winter Ch. Adsorption of superplasticizers on cement in presence retartders. GdCh-Monographie, 2003. 27:55-64.

Sachsenhauser B. Diploma thesis. Technische Universität München; Germany, 2005.

Plank J., Hirsch Ch., Winter Ch., Chatziagorastou P. News about the effect of polycarboxylates-based solvent. ibausil Tagungsband, 2003. 15:1393-408.

Plank J., Hirsch Ch. Superplasticizer adsorption on synthetic ettringite. Seventh CANMET/ACI Conference on Superplasticizers in Concrete. Berlin, Germany, 2003. SP-217(ACI):283-98.

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Published

2015-08-03

How to Cite

[1]
G. Bassioni, “GLOBAL WARMING AND CONSTRUCTION ASPECTS”, ETR, vol. 2, pp. 78–86, Aug. 2015, doi: 10.17770/etr2009vol2.1013.